In 2014 – 16, UK Ministry of Defence (MOD) commissioned a research study into the benefits of embedding a continuous learning culture (CLC), where the whole workforce is actively engaged in promoting and supporting workplace learning. The study identified key benefits associated with a CLC, which related to development of trainer capability, delivery of effective and efficient training, and wider enablement of organisational learning. Leadership of learning was identified as a critical factor in realising these benefits, as it put in place the necessary organisational conditions, mechanisms and hierarchies that enabled a CLC to develop and thrive. The study recommended that roles and responsibilities for leading learning should be made explicit in the workplace, and individuals should be equipped with the right knowledge, skills and resources to be able to engage effectively with these roles. This paper draws on new research undertaken during 2016 – 17 on behalf of UK MOD by RINA Consulting Defence Ltd (formerly Edif ERA) and the University of Leicester, which followed up on the findings of this earlier research with a focus on developing leadership of learning in the workplace. Literature review and case study research with both military and civilian organisations was used to gather qualitative data on the behaviours used by leaders of learning at different levels of management, from senior manager to work supervisor. Options were then considered for developing leadership of learning behaviours across Defence organisations, using learning pathways which included both formal training interventions and informal workplace learning activities. The paper describes leadership of learning behaviours and their impact on organisational learning culture, and explains how organisations could develop these behaviours in the workforce using learning pathways which exploit the organisation’s existing leadership and management training resources. The findings have applicability for all organisations seeking to develop a learning culture that fosters innovation and organisational competitiveness.